Research:

H2-mediated C-C Coupling

Sat, 13 Aug 2011 17:25:08 -0500

Natural Product Synthesis

Fri, 12 Aug 2011 16:41:31 -0500

Nucleophilic Catalysis

Tue, 22 Mar 2011 10:01:15 -0500

Cat. Conj. Addition / Trapping

Mon, 21 Mar 2011 00:00:00 -0500

"Desymmetrization of Enone-Diones via Rhodium Catalyzed Catalytic Diastereo- and Enantioselective Tandem Conjugate Addition-Aldol Cyclization" Bocknack, B. M.; Wang, L.-C.; Krische, M. J. Proc. Nat. Acad. Sci. 2004, 101, 5421.

"Copper Catalyzed Tandem Conjugate Addition-Electrophilic Trapping: Ketones, Esters and Nitriles as Terminal Electrophiles" Agapiou, K.; Cauble, D. F.; Krische, M. J. J. Am. Chem. Soc. 2004, 126, 4528.

"Diastereo- and Enantioselective Catalytic Carbometallative Aldol Cycloreduction: Tandem Conjugate Addition-Aldol Cyclization" Cauble, D. F.; Gipson, J. D.; Krische, M. J. J. Am. Chem. Soc. 2003, 125, 1110.

Metal-Catalyzed [2+2] Cycloaddition

Sun, 20 Mar 2011 00:00:00 -0500

"A Mechanistic Dichotomy in the Reaction of Gilman Reagents with Conjugated Enones: Partitioning of Electron Transfer and Conjugate Addition Manifolds" Yang, J.; Cauble, D. C.; Berro, A. J.; Bauld, N. L.; Krische, M. J. J. Org. Chem. 2004, 69, 7979.

"Chemically Induced Anion Radical Cycloadditions: Intramolecular Cyclobutanation of bis(Enones) via Homogeneous Electron Transfer" Yang, J.; Felton, G. A. N.; Bauld, N. L.; Krische, M. J. J. Am. Chem. Soc. 2004, 126, 1634.

"Diastereoselective Cycloreductions and Cycloadditions Catalyzed by Co(dpm)2/Silane (dpm = 2,2,6,6-tetramethyl-heptane-3,5-dionate): Mechanism and Partitioning of Hydrometallative vs. Anion Radical Pathways" Wang, L.-C.; Jang, H.-Y.; Roh, Y.; Schultz, A. J.; Wang, X.; Lynch, V.; Krische, M. J. J. Am. Chem. Soc. 2002, 124, 9448.

"Anion Radical Chain Cycloaddition of Tethered Enones: Intramolecular Cyclobutanation and Diels-Alder Cycloaddition" Roh, Y.; Jang, H.-Y.; Bauld, N. L.; Krische, M. J. Org. Lett. 2002, 4, 611.

"Diastereoselective Metal Catalyzed [2+2]Cycloaddition of Tethered Enones" Baik, T.-G.; Wang, L.-C.; Luiz, A.-L.; Krische, M. J. J. Am. Chem. Soc. 2001, 123, 6716.