H2-mediated C-C Coupling
“Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines and Alcohols: Site-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines,” Wang, G.; Franke, J.; Ngo, C. Q.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, In Press.

“A Metallacycle Fragmentation Strategy for Vinyl Transfer from Enol Carboxylates to Secondary Alcohol C-H Bonds via Osmium or Ruthenium Catalyzed Transfer Hydrogenation,” Park, B. Y.; Luong, T.; Sato, H. J. Am. Chem. Soc. 2015, 137, In Press.

“Ruthenium(0) Catalyzed Endiyne-α-Ketol [4+2] Cycloaddition: Convergent Assembly of Type II Polyketide Substructures,” Saxena, A.; Perez, F.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 5883.

“Enantioselective Ruthenium Catalyzed Carbonyl Allylation via Alkyne-Alcohol C-C Bond Forming Transfer Hydrogenation: Allene Hydrometallation vs. Oxidative Coupling,” Liang, T.; Nguyen, K. D.; Zhang, W.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 3164.

“Ruthenium Catalyzed C-C Coupling of Fluorinated Alcohols with Allenes to Form All-Carbon Quaternary Centers: Dehydrogenation at the Energetic Limit of β-Hydride Elimination,” Sam, B.; Luong, T.; Krische, M. J. Angew. Chem. Int. Ed. 2015, 54, 5465.

“Ruthenium Catalyzed C-C Coupling of Amino Alcohols with Dienes via Transfer Hydrogenation: Redox-Triggered Imine Addition and Related Hydroaminoalkylations,” Chen, T.-Y.; Tsutsumi, R.; Montgomery, T. P.; Volchkov, I. Krische, M. J. J. Am. Chem. Soc. 2015, 137, 1798.

“Catalyst-Directed Diastereo- and Site-Selectivity in Successive Nucleophilic and Electrophilic Allylations of Chiral 1,3-Diols: Protecting Group-Free Synthesis of 4-Hydroxy-2,6-cis- or trans-Pyrans,” Shin, I.; Wang, G.; Krische, M. J. Chem. Eur. J. 2014, 13382.
“Alkynes as Allylmetal Equivalents in Redox-Triggered C-C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium Catalyzed Propargyl C-H Activation,” Park, B. Y.; Nguyen, K. D.; Chaulagain, M. R.; Komanduri, V.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 11902.
“Redox-Triggered C-C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation,” Feng, J.; Garza, V. J.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 8911.
“Benzannulation via Ruthenium Catalyzed Diol-Diene [4+2] Cycloaddition: One- and Two-Directional Syntheses of Fluoranthenes and Acenes,” Geary, L. M.; Chen T.-Y.; Montgomery, T. P.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 5920.
“Redox-Triggered C-C Coupling of Diols and Alkynes: Synthesis of β,γ-Unsaturated α-Hydroxyketones and Furans via Ruthenium Catalyzed Hydrohydroxyalkylation,” McInturff, E. L.; Nguyen, K. D.; Krische, M. J. Angew. Chem. Int. Ed. 2014, 53, 3232.
“Ruthenium Catalyzed Hydrohydroxyalkylation of Acrylates with Diols and α-Hydroxycarbonyl Compounds to Form Spiro- and α-Methylene-γ-Butyrolactones,” McInturff, E. L.; Mowat, J.; Waldeck, A. R.; Krische, M. J. J. Am. Chem. Soc. 2013, 135, 17230.
“Ruthenium Catalyzed Hydrohydroxyalkylation of Isoprene Employing Heteroaromatic Secondary Alcohols: Isolation and Reversible Formation of the Putative Metallacycle Intermediate,” Park, B. Y.; Montgomery, T. P.; Garza, V.; Krische, M. J. J. Am. Chem. Soc. 2013, 135, 16320.
“Direct C-C Coupling of α-Olefins and Styrenes to 3-Hydroxy-2-oxindoles by Ruthenium Catalyzed Hydrohydroxyalkylation: Byproduct-Free Conversion of Secondary to Tertiary Alcohols,” Yamaguchi, E.; Mowat, J.; Luong, T.; Krische, M. J. Angew. Chem. Int. Ed. 2013, 52, 8428.
“Ruthenium Catalyzed Reductive Coupling of Paraformaldehyde to Trifluoromethyl Allenes: CF3-Bearing All-Carbon Quaternary Centers,” Sam, B.; Montgomery, T. P. Krische, M. J. Org. Lett. 2013, 15, 3790.
“Ruthenium Catalyzed Hydroaminoalkylation of Isoprene via Transfer Hydrogenation: Byproduct-free Prenylation of Hydantoins,” Schmitt, D. C.; Lee, J.; Dechert-Schmitt, A.-M. R. Yamaguchi, E.; Krische, M. J. Chem. Comm. 2013, 6096.
“Successive C-C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed [4+2] Cycloaddition across the Diol, Hydroxycarbonyl or Dione Oxidation Levels,” Geary, L. M.; Glasspoole, B. W.; Kim, M. M. Krische, M. J. J. Am. Chem. Soc. 2013, 135, 3796.
“Site-Selective Primary Alcohol Dehydrogenation Enables Protecting Group-Free Diastereoselective C-C Coupling of 1,3-Glycols and Allyl Acetate,” Dechert-Schmitt, A.-M. R.; Schmitt, D. C.; Krische, M. J. Angew. Chem. Int. Ed. 2013, 52, 3195.
“Regiodivergent Reductive Coupling of 2-Substituted Dienes to Formaldehyde Employing Ruthenium or Nickel Catalysts: Hydrohydroxymethylation via Transfer Hydrogenation,” Köpfer, A.; Sam, B.; Breit, B.; Krische, M. J. Chem. Sci. 2012, 4, 1876.
“Chiral Anion Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium Catalyzed Butadiene Hydrohydroxyalkylation,” McInturff, E. L.; Yamaguchi, E.; Krische, M. J. J. Am. Chem. Soc. 2012, 134, 20628.
“Iridium-Catalyzed Allylation of Chiral β-Stereogenic Alcohols: Bypassing Discrete Formation of Epimerizable Aldehydes,” Org. Lett. Schmitt, D. C.; Dechert-Schmitt, A.-M. R.; Krische, M. J. Org. Lett. 2012, 14, 6302.
“Direct, Redox Neutral Prenylation and Geranylation of Secondary Carbinol C-H Bonds: C4 Regioselectivity in Ruthenium Catalyzed C-C Couplings of Dienes to α-Hydroxy Esters,” Leung, J. C.; Geary, L. M.; Chen, T.-Y.; Zbieg, J. R.; Krische, M. J. J. Am. Chem. Soc. 2012, 134, 15700.
“Ruthenium Catalyzed Reductive Coupling of 1,3-Enynes and Aldehydes via Transfer Hydrogenation: anti-Diastereoselective Carbonyl Propargylation,” Geary, L. M.; Leung, J. C.; Krische, M. J. Chem. Eur. J. 2012, 18, 16823.
“Enantioselective Conversion of Primary Alcohols to α-Methylene Butyrolactones via Iridium Catalyzed C-C Bond Forming Transfer Hydrogenation: 2-(Alkoxycarbonyl)allylation,” Montgomery, T. P.; Hassan, A.; Park, B. Y.; Krische, M. J. J. Am. Chem. Soc. 2012, 134, 11100.
“Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides,” Woo, S. K.; Geary, L. M.; Krische, M. J. Angew. Chem. Int. Ed. 2012, 51, 7830.
“Consecutive Iridium Catalyzed C-C and C-H Bond Forming Hydrogenations for the Diastereo- and Enantioselective Synthesis of syn-3-Fluoro-1-Alcohols: C-H (2-Fluoro)allylation of Primary Alcohols,” Hassan, A.; Montgomery, T. P.; Krische, M. J. Chem. Comm. 2012, 4692.
“Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene,” Zbieg, J. R.; Yamaguchi, E.; McInturff, E. L.; Krische, M. J. Science 2012, 336, 324.
“Diastereo- and Enantioselective Iridium Catalyzed Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level: 1,3-Enynes as Allenylmetal Equivalents,” Geary, L. M.; Woo, S. K.; Leung, J. C. Krische, M. J. Angew. Chem. Int. Ed. 2012, 51, 2972.
“Polarity Inversion of Donor-Acceptor Cyclopropanes: Disubstituted -Lactones via Enantioselective Iridium Catalysis,” Moran, J.; Smith, A. G.; Carris, R. M.; Johnson, J. S.; Krische, M. J. J. Am. Chem. Soc. 2011, 133, 18618.
“Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction,” Gao, X.; Han, H.; Krische, M. J. J. Am. Chem. Soc. 2011, 133, 12795.
“Alkyne-Aldehyde Reductive C-C Coupling via Ruthenium Catalyzed Transfer Hydrogenation: Regio- and Stereoselective Carbonyl Vinylation to Form Trisubstituted Allylic Alcohols in the Absence of Vinylmetal Reagents,” Leung, J. C.; Patman, R. L.; Sam, B.; Krische, M. J. Chem. Eur. J. 2011, 17, 12437.
“Catalytic Enantioselective Grignard Nozaki-Hiyama Methallylation from the Alcohol Oxidation Level: Chloride Compensates for π-Complex Instability,” Hassan, A.; Townsend, I. A.; Krische, M. J. Chem. Comm. 2011, 10028.
“Diastereo- and Enantioselective Ruthenium Catalyzed Hydrohydroxyalkylation of 2-Silyl-Butadienes: Carbonyl syn-Crotylation from the Alcohol Oxidation Level,” Zbieg, J. R.; Moran, J.; Krische M. J. J. Am. Chem. Soc. 2011, 133 (27), 10582.
“Iridium Catalyzed anti-Diastereo- and Enantioselective Carbonyl (α-Trifluoromethyl)allylation from the Alcohol or Aldehyde Oxidation Level,” Gao, X.; Zhang, Y. J.; Krische, M. J. Angew. Chem. Int. Ed. 2011, 50, 4173.
“Enantioselective Iridium Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates,” Zbieg, J. R.; Hassan, A.; Kim, I.-S.; Krische, M. J. Angew. Chem. Int. Ed. 2011, 50, 3493.
“Amplification of anti-Diastereoselectivity via Curtin-Hammett Effects in Ruthenium Catalyzed Hydrohydroxyalkylation of 1,1-Disubstituted Allenes: Diastereoselective Formation of All-Carbon Quaternary Centers,” Zbieg, J. R.; McIntuff, E. L.; Leung, J. C.; Krische, M. J. J. Am. Chem. Soc. 2011, 133, 1141.
"Direct Catalytic C-C Coupling of Methanol Employing a Homogeneous Iridium Complex: Hydrohydroxymethylation of Allenes," Moran, J.; Preetz, A.; Mesch, R. A.; Krische, M. J. Nature Chem. 2011, 3, 287.
“Total Synthesis of (+)-Roxaticin via C-C Bond Forming Transfer Hydrogenation: A Departure from Stoichiometric Chiral Reagents, Auxiliaries and Premetallated Nucleophiles in Polyketide Construction,” Han, S. B.; Hassan, A.; Kim, I. S.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 15559.
"Iridium Catalyzed anti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level" Han, S. B.; Gao, X.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 9153.
"Direct Ruthenium Catalyzed C-C Coupling of Ethanol: Diene Hydro-Hydroxyethylation to Form All Carbon Quaternary Center" Han, H.; Krische, M. J. Org. Lett. 2010, 12, 2844.
"Allenamide Hydro-Hydroxyalkylation: 1,2-Aminoalcohols via Ruthenium Catalyzed Carbonyl anti-Aminoallylation" Zbieg, J. R.; McInturff, E.; Krische, M. J. Org. Lett. 2010, 12, 2514.
"anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates" Zhang, Y. J.; Yang, J. H.; Kim, S. H.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 4562.
"Diastereo- and Enantioselective anti-Alkoxyallylation Employing Allylicgem-Dicarboxylate as Ally Donors via Iridium Catalyzed Transfer Hydorgenation." Han, S. B.; Han, H.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 1760.
"All Carbon Quaternary Centers via Ruthenium Catalyzed Hydroxymethylation of 2-Substituted Butadiene Mediated by Formaldehyde: Beyond Hydroformylation." Smejkal, T.; Han, H.; Breit, B.; Krische, M. J. J. Am. Chem. Soc. 2009, 131, 10366.
"Enantioselective Allylation Crotylation and Reverse Prenylation of Substituted Isatin via Iridium Catalyzed C-C Bond Forming Transfer Hydrogenation." Itoh, J.; Han, S. B.; Krische, M. J. Angew. Chem. Int. Ed. 2009, 48, 6313.
"Elongation of 1,3-Polyols via Iterative Catalyst-Directed Carbonyl Allylation from the Alcohol Oxidation Level." Hassan, A.; Lu, Y.; Krische, M. J. Org. Lett. 2009, 11, 3112.
"1,n-Glycols as Dialdehyde Equivalents in Iridium Catalyzed Enantioselective Carbonyl Allylation and Iterative Two-Directional Assembly of 1,3-Polyols." Lu, Y.; Kim, I.-S.; Hassan, A.; Del Valle, D. J.; Krische, M. J. Angew. Chem. Int. Ed. 2009, 48, 5018.
"Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor." Han, S. B.; Kim, I.-S.; Han, H.; Krische, M. J. J. Am. Chem. Soc. 2009, 131, 6916.
"anti-Aminoallylation of Aldehydes via Ruthenium Catalyzed Transfer Hydrogenative Coupling of Sulfonamido Allenes: 1,2-Aminoalcohols ." Skucas, E.; Zbieg, J. R.; Krische, M. J. J. Am. Chem. Soc. 2009, 131, 5054.
"Direct C-Vinylation of Alcohols or Aldehydes Employing Alkynes as Vinyl Donors: A Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation." Patman, R. L.; Chaulagain, M. R.; Williams, V. M.; Krische, M. J. J. Am. Chem. Soc. 2009, 131, 2066.
"anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: a-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagent." Kim, I. S.; Han, S. B.; Krische, M. J. J. Am. Chem. Soc. 2009, 131, 2514.
"Hydroacylation of 2-Butyne from the Alcohol or Aldehyde Oxidation Level via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation." Williams, V. M.; Leung, J. C.; Patman, R. L.; Krische, M. J. Tetrahedron 2009, 65, 5024.
"Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonly Addition." Kim, I. S.; Nagi, M. -Y.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 14891.
"Diene Hydroacylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed C-C Bond-Forming Transfer Hydrogenation: Synthesis of β,γ-Unsaturated Ketones." Shibahara, F.; Bower, J. F.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 14120.
"Branch-Selective Reductive Coupling of 2-Vinyl Pyridines and Imines via Rhodium Catalyzed C-C Bond Forming Hydrogenation." Komanduri. V.;Grant, C. D.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 12592.
"Catalyst-Directed Diastereoselectivity in Hydrogenative Coupling of Acetylene to α-Chiral Aldehydes: Formal Synthesis of All Eight L-Hexoses." Han, S. B.; Kong, J.-R.; Krische, M. J. Org. Lett. 2008, 10, 4133.
"Ruthenium Catalyzed C-C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes." Ngai, M. -Y.; Skucas, E.; Krische, M. J. Org. Lett. 2008, 10, 2705.
"Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Enynes as Surrogates to Preformed Allenylmetal Reagents: A Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation." Patman, R. L.; Williams, V. M.; Bower, J. F.; Krische, M. J. Angew. Chem. Int. Ed. 2008, 47, 5220.
"Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate." Kim, I. S.; Ngai, M, -Y.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 6340.
"Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents." Shibahara, F.; Bower, J. F.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 6338.
"Diastereo- and Enantioselective Hydrogenative Aldol Coupling of Vinyl Ketones: Design of an Effective Monodentate TADDOL-Like Phosphonite Ligand." Bee C.; Han, S. B.; Hassan, A.; Ioda, H.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 2746.
"Iridium Catalyzed C-C Coupling via Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Cyclohexadiene." Bower, J. F.; Patman, R. L.; Krische, M. J. Org. Lett. 2008, 10, 1033.
"Catalytic C-C Coupling via Transfer Hydrogenation: Reverse Prenylation, Crotylation and Allylation from the Alcohol or Aldehyde Oxidation Level." Bower, J.; Skucas, E.; Patman, R. L.; Krische, M. J. J. Am. Chem. Soc. 2007, 129, 15134.
"Enantioselective Iridium Catalyzed Imine Vinylation: Optically Enriched Allylic Amines via Alkyne-Imine Reductive Coupling Mediated by Hydrogen." Ngai, M.-Y.; Barchuk, A.; Krische, M. J. J. Am. Chem. Soc. 2007, 129, 12644.
"Carbonyl Allylation in the Absence of Preformed Allyl Metal Reagents: Reverse Prenylation via Iridium Catalyzed Hydrogenative Coupling of Dimethylallene." Skucas, E.; Bower, J.; Krische, M. J. J. Am. Chem. Soc. 2007, 129, 12678.
"Enantioselective Reductive Coupling of 1,3-Enynes to Glyoxalates Mediated by Hydrogen: Asymmetric Synthesis of β,γ-Unsaturated α-Hydroxy Esters." Hong, Y.-T.; Cho, C.-W.; Skucas, E.; Krische, M. J. Org. Lett. 2007, 9, 3745.
"Allylic Amine via Iridium Catalyzed C-C Bond Forming Hydrogenation: Imine Vinylation in the Absence of Stoichiometric Byproducts or Metallic Reagents." Barchuk, A.; Ngai, M.-Y.; Krische, M. J. J. Am. Chem. Soc. 2007, 129, 8432.
"Enantioselective Reductive Coupling of Acetylene to N-Arylsulfonyl Imines via Rhodium Catalyzed C-C Bond Forming Hydrogenation: (Z)-Dienyl Allylic Amines." Skucas, E.; Kong, J.-R.; Krische, M. J. J. Am. Chem. Soc. 2007, 129, 7242.
"Iridium Catalyzed C-C Bond Forming Hydrogenation: Direct Regioselective Reductive Coupling of Alkyl-Substituted Alkynes to Activated Ketones." Ngai, M.-Y.; Barchuk, A.; Krische, M. J. J. Am. Chem. Soc. 2007, 129, 280.
"Asymmetric Induction in Hydrogen-Mediated Reductive Aldol Additions to α-Amino Aldehydes Catalyzed by Rhodium: Selective Formation of syn-Stereotriads Directed by Intramolecular Hydrogen-Bonding." Jung, C.-K.; Krische, M. J. J. Am. Chem. Soc. 2006, 128, 17051.
"Enantioselective Reductive Coupling of 1,3-Enynes to Heterocyclic Aromatic Aldehydes and Ketones via Rhodium Catalyzed Asymmetric Hydrogenation: Mechanistic Insight into the Role of Brønsted Acid Additives." Komanduri, V.; Krische, M. J. J. Am. Chem. Soc. 2006, 128, 16448.
"Catalytic Carbonyl (Z)-Dienylation via Multicomponent Reductive Coupling of Acetylene to Aldehydes and α-Ketoesters Mediated by Hydrogen: Carbonyl Insertion into Cationic Rhodocyclopentadienes." Kong, J.-R.; Krische, M. J. J. Am. Chem. Soc. 2006, 128, 16040.
"Branched-Selective Intermolecular Hydroacylation: Hydrogen-Mediated Coupling of Anhydrides to Styrenes and Activated Olefins." Hong, Y.-T.; Barchuk, A.; Krische, M. J. Angew. Chem. Int. Ed. 2006, 128, 6885.
"Reductive Aldol Coupling of Divinyl Ketones via Rhodium Catalyzed Hydrogenation: syn-Diastereoselective Construction of β-Hydroxyenones." Han, S. B.; Krische, M. J. Org. Lett. 2006, 8, 5657.
"Highly Enantioselective Reductive Cyclization of Acetylenic Aldehydes via Rhodium Catalyzed Asymmetric Hydrogenation." Rhee, J.-U.; Krische, M. J. J. Am. Chem. Soc. 2006, 128, 10674.
"α-Hydroxy Esters via Enantioselective Hydrogen-Mediated C-C Coupling: Regiocontrolled Reactions of Silyl-Substituted 1,3-Diynes." Cho, C.-W.; Krische, M. J. Org. Lett. 2006, 8, 3873.
"An Approach to the Bryostatin Recognition Domain via Enantioselective Rhodium Catalyzed Reductive Coupling Mediated by Hydrogen." Cho, C.-W.; Krische, M. J. Org. Lett. 2006, 8, 891.
"Hydrogen-Mediated Aldol Reductive Coupling of Vinyl Ketones Catalyzed by Rhodium: High Syn-Selectivity through the Effect of Tri-2-furylphosphine," Jung, C.-K.; Garner, S. A.; Krische, M. J. Org. Lett. 2006, 8, 519.
"Highly Enantioselective Direct Reductive Coupling of Conjugated Alkynes and α-Ketoesters via Rhodium Catalyzed Asymmetric Hydrogenation," Kong, J.-R.; Ngai, M.-Y.; Krische, M. J. J. Am. Chem. Soc. 2006, 128, 718.
"Hydrogen-Mediated Reductive Coupling of Conjugated Alkynes with Ethyl (N-sulfinyl)iminoacetates: Diastereoselective Synthesis of Unnatural α-Amino Acids via Rhodium Catalyzed C-C Bond Forming Hydrogenation." Kong, J.-R.; Cho, C.-W.; Krische, M. J. J. Am. Chem. Soc. 2005, 127, 11269.
"Enantioselective Reductive Cyclization of 1,6-Enynes via Rhodium Catalyzed Asymmetric Hydrogenation: C-C Bond Formation Precedes Hydrogen Activation." Jang, H.-Y.; Hughes, F. W.; Gong, H.; Zhang, J.; Brodbelt, J. S.; Krische, M. J. J. Am. Chem. Soc. 2005, 127, 6174.
"Rhodium Catalyzed Reductive Cyclization of 1,6-Diynes and 1,6-Enynes Mediated by Hydrogen: Catalytic C-C Bond Formation via Capture of Hydrogenation Intermediates." Jang, H.-Y.; Krische, M. J. J. Am. Chem. Soc. 2004, 126, 7875.
"Hydrogen-Mediated C-C Bond Formation: Catalytic Regio- and Stereoselective Reductive Condensation of α-Keto Aldehydes and 1,3-Enynes." Jang, H.-Y.; Huddleston, R. R.; Krische, M. J. J. Am. Chem. Soc. 2004, 126, 4664.
"Catalytic Addition of Metallo-Aldehyde Enolates to Ketones: A New C-C Bond Forming Hydrogenation." Koech, P. K.; Krische, M. J. Org. Lett. 2004, 6, 691.
"Metallo-Aldehyde Enolates via Enal Hydrogenation: Catalytic Cross Aldolization with Glyoxal Partners as Applied to the Synthesis of 3,5-Disubstituted Pyridazines." Marriner, G. A.; Garner, S. A.; Jang, H.-Y.; Krische, M. J. J. Org. Chem. 2004, 69, 1380.
"First Catalytic Reductive Coupling of 1,3-Diynes to Carbonyl Partners: A New Regio- and Enantioselective C-C Bond Forming Hydrogenation." Huddleston, R. R.; Jang, H.-Y. Krische, M. J. J. Am. Chem. Soc. 2003, 125, 11488.
"Enolate Generation under Hydrogenation Conditions: Catalytic Aldol Cycloreduction of Keto-Enones." Huddleston, R. R.; Krische, M. J. Org. Lett. 2003, 5, 1143.
"Use of Elemental Hydrogen for the Reductive Generation of Enolates from Enones: Catalytic C-C Bond Formation under Hydrogenative Conditions." Jang, H.-Y.; Huddleston, R. R.; Krische, M. J. J. Am. Chem. Soc. 2002, 124, 15156.